Understanding PFAS

 

The CTC laboratories provide analyses to search for and detect PFAS (per- and polyfluoroalkyl substances), a large group of over 4,000 chemical compounds. Used since the 1950s in various industrial fields and everyday consumer products, PFAS have long been valued for their remarkable physical and chemical properties, such as heat resistance and waterproofness, as well as their capacity to stabilise products over time. 

However, their stability and durability have become major concerns for the environment and public health, due to their cumulative effect and non-degradability. This is why these substances are often described as “forever chemicals”. 

To address this issue, the authorities are strengthening the legislation on the use of these compounds and increasing checks to detect the presence of PFAS in products. 

Our experts are available to handle your questions or analysis requests. 

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Where are PFAS found ? 

Due to their varied use and their persistence, all environments can be affected by contaminations: water, air, soil, the food chain, and consumer goods. 

  • Where water is concerned, the sectors targeted by the Ministerial Decree of 20/06/2023 (including tanneries) 
  • The consumer goods industry 

 

A closer look 

  • PFAS: per- and polyfluoroalkyl substances 
  • Carbon chain (of variable length) on which the hydrogen (H) atoms have been replaced by fluorine (F) atoms 
  • Very strong carbon-fluorine (C-F) chemical bond 
  • Several thousand compounds made and used over the past decades 

 

Numerous properties 

  • Waterproof/stain proof: rain gear, technical materials, textiles, upholstery fabrics 
  • Non-stick: kitchen utensils 
  • Fire proof: technical materials, fire-retardant foams 
  • … 

 

Impact

  • Very long lifespan 
  • Very persistent in the environment 
  • Significant health consequences 

 

Regulations 

  • PFOS and PFOA prohibited since 2009 and 2020 respectively 
  • Since 2023, new French legislation on water quality (Ministerial Decree of 20/06/2023) 
  • More stringent REACh regulations 

 

What you absolutely must do to comply with water regulations 

  • Perform an inventory of the PFAS that are or have been present in your facility 
  • During three consecutive months, take a sample of the discharges concerned (effluents from the site’s industrial activity discharged directly or indirectly into the natural environment, and rain water discharges likely to be polluted) 
  • Carry out an accredited analysis of the 20 PFAS in the effluents concerned as well as those from the technically quantifiable inventory 
  • The analysis of the AOF index in the effluents concerned, index parameter concerning the total organic fluorine content 

 

Category Sector of Activity
2330 Dyeing, printing, finishing, coating, bleaching, and washing-off of textile materials
2345 Use of solvents for dry cleaning and treatment of textiles or garments
2350 Tanneries, taweries, and any operation involving the preparation of hides and skins
2351 Dyeing and pigmentation of hides
2567 Galvanisation, tinning of metals or metallic coating of any material by a process other than chemical or electrolytic
2660 Polymers (plastics, rubber, elastomers, synthetic resins and adhesives) – manufacturing or regeneration
2661 Polymers (plastics, rubber, elastomers, synthetic resins and adhesives) – processing
2750 Collective wastewater treatment plant for industrial effluents originating from at least one classified facility subject to authorisation
2752 Mixed wastewater treatment plant (receiving both domestic and industrial wastewater) with a nominal treatment capacity of at least 10,000 population equivalents (PE), when the load exceeds 70% of the plant’s capacity in COD
2760 Waste storage facility
2790 Hazardous waste treatment facility
2791 Non-hazardous waste treatment facility
2795 Facility for washing drums, containers, and transport tanks for foodstuffs or hazardous substances or mixtures
3120 Petroleum and gas refining
3230 Processing of ferrous metals
3260 Surface treatment of metals or plastics using an electrolytic or chemical process
3410 Industrial-scale manufacturing by chemical or biological transformation of organic chemical products
3420 Industrial-scale manufacturing by chemical or biological transformation of inorganic chemical products
3440 Industrial-scale manufacturing by chemical or biological transformation of plant protection products or biocides
3450 Industrial-scale manufacturing by chemical or biological transformation of pharmaceutical products, including intermediates
3510 Disposal or recovery of hazardous waste
3531 Disposal of non-inert non-hazardous waste with a capacity exceeding 50 tonnes/day
3532 Recovery, or a mix of recovery and disposal, of non-inert non-hazardous waste with a capacity exceeding 75 tonnes/day
3540 Waste storage installations
3560 Underground storage of hazardous waste with a total capacity exceeding 50 tonnes
3610 Manufacture, in industrial installations, of pulp from wood or other fibrous materials, paper or cardboard, or wood-based panels
3620 Pre-treatment (washing, bleaching, mercerisation) or dyeing of textile fibres or textiles
3630 Tanning of hides, with a processing capacity exceeding 12 tonnes of finished products per day
3670 Surface treatment of materials, objects or products using organic solvents
3710 Wastewater treatment
4713 Fluorine (CAS number 7782-41-4)

 

List of the 20 compulsory PFAS 

Molecule CAS number Sandre code
Perfluorobutanoic acid PFBA 375-22-4 5980
Perfluoropentanoic acid PFPeA 2706-90-3 5979
Perfluorohexanoic acid PFHxA 307-24-4 5978
Perfluoroheptanoic acid PFHpA 375-85-9 5977
Perfluorooctanoic acid PFOA 335-67-1 5347
Perfluorononanoic acid PFNA   375-95-1 6508
Perfluorodecanoic acid PFDA 335-76-2 6509
Perfluoroundecanoic acid PFUnDA 2058-94-8 6510
Perfluorododecanoic acid PFDoDA 307-55-1 6507
Perfluorotridecanoic acid PFTrDA 72629-94-8 6549
Perfluorobutanesulfonic acid PFBS 59933-66-3 6025
Perfluoropentanesulfonic acid PFPeS 2706-91-4 8738
Perfluorohexanesulfonic acid PFHxS 355-46-4 6830
Perfluoroheptanesulfonic acid PFHpS 375-92-8 6542
Perfluorooctanesulfonate PFOS 45298-90-6 6561
Perfluorononanesulfonic acid PFNS 68259-12-1 8739
Perfluorodecanesulfonic acid PFDS 335-77-3 6550
Perfluoroundecanesulfonic acid PFUnDS 749786-16-1 8740
Perfluorododecanesulfonic acid PFDoDS 79780-39-5 8741
Perfluorotridecanesulfonic acid PFTrDS 791563-89-8 8742
Perfluorooctanesulfonic acid PFOS 1763-23-1 6560

 

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